4-Anilino-3-nitro-N-phenyl­benzamide

نویسندگان

  • Guihua Chen
  • Jian Yan
چکیده

In the title compound, C(19)H(15)N(3)O(3), the anilino and benzamide rings make dihedral angles of 10.66 (16) and 50.39 (16)°, respectively, with the nitro-substituted benzene ring. The nitro group is slightly twisted by 11.49 (17)° with respect to the attached benzene ring. There is an intra-molecular N-H⋯O hydrogen bond forming an S(6) ring. In the crystal, weak inter-molecular N-H⋯O and C-H⋯O hydrogen bonds link the mol-ecules into a chain parallel to the b axis. Futhermore, weak slipped π-π inter-actions [centroid-centroid distance = 3.819 (2) Å, inter-planar distance = 3.567 Å and offset angle [how is the offset angle defined?] = 21°] between the anilino ring and its symmetry-related counterpart may help to stabilize the packing.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

2-Hy­droxy-5-nitro-N-phenyl­benzamide

The mol-ecule of the title compound, C(13)H(10)N(2)O(4), is almost planar with a dihedral angle between the benzene rings of 1.99 (13)°. The nitro group and its parent benzene ring are oriented at a dihedral angle of 7.6 (3)°. Intra-molecular C-H⋯O and N-H⋯O hydrogen bonds form two planar S(6) motifs. Inter-molecular O-H⋯O=C hydrogen bonds join mol-ecules into chains extending along the c axis.

متن کامل

2-Hydr­oxy-3-nitro-N-phenyl­benzamide

The asymmetric unit of the title compound, C(13)H(10)N(2)O(4), contains two crystallographically independent mol-ecules. The aromatic rings are oriented at dihedral angles of 24.39 (3) and 7.47 (3)° in the two mol-ecules and intra-molecular N-H⋯O and O-H⋯O hydrogen bonds result in the formation of two planar six-membered rings. In the crystal structure, inter-molecular O-H⋯O and C-H⋯O hydrogen ...

متن کامل

2-Anilino-N-methyl-N-phenyl­benzamide

The title compound, C(20)H(18)N(2)O, is composed of three aromatic rings, the dihedral angles between the phenyl and benzamide rings, and between the benzamide and aniline rings being 59.86 (9) and 46.57 (10)°, respectively. The mol-ecular structure is stabilized by an intra-molecular N-H⋯O hydrogen bond involving the amino H atom and the benzamide carbonyl O atom. In the crystal structure, C-H...

متن کامل

ONE STEP SYNTHESIS OF ANILINO ALKYL-NSUBSTITUTED PHTHALIMIDES RELATED TO BENZOISOQUINOLINE-1,3-DIONES (1)

A facile one step synthesis of anilino alky1-N-substituted phthalimide I is reported. The following compounds belonging to this series were made: 1. (anilino-N-ethyl) phthalimide 8 2. (3,4, 5-trimethoxy anilino-N-ethyl) phthalimide 6 3. (3,4, 5-trimethoxy anilino-N-propyl) phthalimide 7 4. N-(ethyl phthalirnido-p-amino benzoyl) glutamic acid diethyl ester 10 5. N-(propyl phthalimido-p-ami...

متن کامل

4-Anilino-3-nitro­benzonitrile

In the title compound, C(13)H(9)N(3)O(2), the aromatic rings are twisted with respect to each other, making a dihedral angle of 49.41 (9)°. The nitro group and the nitrile group are nearly in the plane of the benzonitrile ring, the largest deviation from the plane being 0.123 (1) Å. There is an intra-molecular N-H⋯O hydrogen bond forming an S(6) ring. Weak inter-molecular C-H⋯O hydrogen bonds l...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره 66  شماره 

صفحات  -

تاریخ انتشار 2010